Clarify that RUST_MIN_STACK may be internally cached
For larger applications it's important that users set `RUST_MIN_STACK` at the start of their program because [`min_stack`](7d3e03666a/library/std/src/sys_common/thread.rs) caches the value. Not doing so can lead to their `env::set_var` call surprisingly not having any effect.
In my own testing `RUST_MIN_STACK` had no effect until I moved it to the top of `main()`. Hopefully this clarification in the docs will help others going forward.
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