Clean up warnings + `unsafe_op_in_unsafe_fn` when building std for armv6k-nintendo-3ds
See #127747
ping `@AzureMarker` `@Meziu`
I could only find one instance needing an extra `unsafe` that was not also shared with many other `unix` targets (presumably these will get covered in larger sweeping changes, I didn't want to introduce churn that would potentially conflict with those). The one codepath I found is shared with `vita` however, so also pinging `@nikarh` `@pheki` `@zetanumbers` just to make sure they're aware of this change.
Also removed one unused import from `process_unsupported` which should simply fix the warning for any target that uses it.