Add notes and examples about non-intuitive PathBuf::set_extension behavior

Basically, passing the empty string will actually remove the extension
instead of setting it to the empty string. This might change what is
considered to be an extension. Additionally, passing an extension that
contains dots will make the path only consider the last part of it to be
the new extension.

library/std/src/path.rs

@@ -1411,7 +1411,8 @@ fn _set_file_name(&mut self, file_name: &OsStr) {
         self.push(file_name);
     }
 
-    /// Updates [`self.extension`] to `extension`.
+    /// Updates [`self.extension`] to `Some(extension)` or to `None` if
+    /// `extension` is empty.
     ///
     /// Returns `false` and does nothing if [`self.file_name`] is [`None`],
     /// returns `true` and updates the extension otherwise.
@@ -1419,6 +1420,20 @@ fn _set_file_name(&mut self, file_name: &OsStr) {
     /// If [`self.extension`] is [`None`], the extension is added; otherwise
     /// it is replaced.
     ///
+    /// If `extension` is the empty string, [`self.extension`] will be [`None`]
+    /// afterwards, not `Some("")`.
+    ///
+    /// # Caveats
+    ///
+    /// The new `extension` may contain dots and will be used in its entirety,
+    /// but only the part after the final dot will be reflected in
+    /// [`self.extension`].
+    ///
+    /// If the file stem contains internal dots and `extension` is empty, part
+    /// of the old file stem will be considered the new [`self.extension`].
+    ///
+    /// See the examples below.
+    ///
     /// [`self.file_name`]: Path::file_name
     /// [`self.extension`]: Path::extension
     ///
@@ -1432,8 +1447,20 @@ fn _set_file_name(&mut self, file_name: &OsStr) {
     /// p.set_extension("force");
     /// assert_eq!(Path::new("/feel/the.force"), p.as_path());
     ///
-    /// p.set_extension("dark_side");
-    /// assert_eq!(Path::new("/feel/the.dark_side"), p.as_path());
+    /// p.set_extension("dark.side");
+    /// assert_eq!(Path::new("/feel/the.dark.side"), p.as_path());
+    ///
+    /// p.set_extension("cookie");
+    /// assert_eq!(Path::new("/feel/the.dark.cookie"), p.as_path());
+    ///
+    /// p.set_extension("");
+    /// assert_eq!(Path::new("/feel/the.dark"), p.as_path());
+    ///
+    /// p.set_extension("");
+    /// assert_eq!(Path::new("/feel/the"), p.as_path());
+    ///
+    /// p.set_extension("");
+    /// assert_eq!(Path::new("/feel/the"), p.as_path());
     /// ```
     #[stable(feature = "rust1", since = "1.0.0")]
     pub fn set_extension<S: AsRef<OsStr>>(&mut self, extension: S) -> bool {